Stable and recyclable Au25 clusters for the reduction of 4-nitrophenol

Atal Shivhare; Stephen J. Ambrose; Haixia Zhang; Randy W. Purves; Robert W. J. Scott

doi:10.1039/C2CC37205C

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Chemical Communications

Issue 3, 2013

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Stable and recyclable Au₂₅ clusters for the reduction of 4-nitrophenol

Atal Shivhare,^a Stephen J. Ambrose,^b Haixia Zhang,^b Randy W. Purves^a^b and Robert W. J. Scott*^a

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Department of Chemistry, University of Saskatchewan, 110 Science Place, Saskatoon, Canada
E-mail: robert.scott@usask.ca ;
Tel: +1-306-966-2017

National Research Council of Canada, 110 Gymnasium Place, Saskatoon, Canada

Chem. Commun., 2013,49, 276-278

DOI: 10.1039/C2CC37205C
Received 02 Oct 2012, Accepted 12 Nov 2012
First published online 13 Nov 2012

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Thiol-stabilized Au₂₅L₁₈ monolayer protected clusters (MPCs) were found to be active for the reduction of 4-nitrophenol. Results suggest that these MPCs are stable catalysts and do not lose their structural integrity during the catalytic process. High stability under the reaction conditions enables the recyclability of these MPCs.

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Atal Shivhare
Stephen J. Ambrose
Haixia Zhang
Randy W. Purves
Robert W. J. Scott

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Chemical Communications

Stable and recyclable Au25 clusters for the reduction of 4-nitrophenol

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Stable and recyclable Au₂₅ clusters for the reduction of 4-nitrophenol