Using structure-directing agents, pore space partitions of a Zn-phosphonocarboxylate framework have been achieved. Selective adsorption of CO2 over N2 has been greatly improved from ca. 9
:1 to 94:1.
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Enhancing CO2 adsorption of a Zn-phosphonocarboxylate framework by pore space partitions
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Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, P. R. China
E-mail: ymzhou@fudan.edu.cn ;
Fax: +86 21 65643925 ;
Tel: +86 21 65642261
E-mail: ymzhou@fudan.edu.cn ;
Fax: +86 21 65643925 ;
Tel: +86 21 65642261
Chem. Commun., 2013,49, 78-80
DOI: 10.1039/C2CC37174J
Received 15 Aug 2012, Accepted 05 Nov 2012
First published online 05 Nov 2012
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