An efficient dehydroxymethylation reaction by a palladium catalyst

Atanu Modak; Togati Naveen; Debabrata Maiti

doi:10.1039/C2CC36951F

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Chemical Communications

Issue 3, 2013

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An efficient dehydroxymethylation reaction by a palladium catalyst

Atanu Modak,^a Togati Naveen^a and Debabrata Maiti*^a

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Department of Chemistry, Indian Institute of Technology, Powai, Mumbai, India
E-mail: dmaiti@chem.iitb.ac.in

Chem. Commun., 2013,49, 252-254

DOI: 10.1039/C2CC36951F
Received 25 Sep 2012, Accepted 09 Oct 2012
First published online 11 Oct 2012

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A general method for selective dehydroxymethylation has been discovered by using widely available Pd(OAc)₂. The present study offers a new synthetic strategy for the regioselective functionalization by employing the steric, electronic and coordinating nature of the hydroxymethyl (–CH₂OH) group temporarily.

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