Anion-driven self-assembly: from discrete cages to infinite polycatenanes step by step

Qihui Chen; Feilong Jiang; Daqiang Yuan; Lian Chen; Guangxun Lyu; Maochun Hong

doi:10.1039/C2CC36921D

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Chemical Communications

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Anion-driven self-assembly: from discrete cages to infinite polycatenanes step by step

Qihui Chen,^a Feilong Jiang,^a Daqiang Yuan,^a Lian Chen,^a Guangxun Lyu^a and Maochun Hong*^a

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State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China
E-mail: hmc@fjirsm.ac.cn ;
Fax: +86 591-83794946 ;
Tel: +86 591-83712460

Chem. Commun., 2013,49, 719-721

DOI: 10.1039/C2CC36921D
Received 24 Sep 2012, Accepted 27 Nov 2012
First published online 28 Nov 2012

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Abstract
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Induced by different anions, two different polycatenanes constructed from Ag₆L₄ units with different conformations have been prepared. Intermediates Ag₆L₄ and Ag₅L₄ are observed to participate in interlocking, and the related possible self-assembly routes are also presented.

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Qihui Chen
Feilong Jiang
Daqiang Yuan
Lian Chen
Guangxun Lyu
Maochun Hong

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