Fabrication of a dye-sensitized solar cell containing a Mg-doped TiO2 electrode and a Br3−/Br− redox mediator with a high open-circuit photovoltage of 1.21 V

Kenji Kakiage; Toru Tokutome; Shinji Iwamoto; Toru Kyomen; Minoru Hanaya

doi:10.1039/C2CC36873K

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Chemical Communications

Issue 2, 2013

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Fabrication of a dye-sensitized solar cell containing a Mg-doped TiO₂ electrode and a Br₃⁻/Br⁻ redox mediator with a high open-circuit photovoltage of 1.21 V

Kenji Kakiage,^a^b Toru Tokutome,^a Shinji Iwamoto,^a^c Toru Kyomen^a^c and Minoru Hanaya*^a^c

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Department of Chemistry and Chemical Biology, Graduate School of Engineering, Gunma University, Tenjin-cho 1-5-1, Kiryu, Japan
E-mail: mhanaya@gunma-u.ac.jp ;
Fax: +81-277-30-1360 ;
Tel: +81-277-30-1360

Human Resource Cultivation Center (HRCC), Gunma University, Tenjin-cho 1-5-1, Kiryu, Japan

International Education and Research Center for Silicon Science (Silicon Center), Graduate School of Engineering, Gunma University, Tenjin-cho 1-5-1, Kiryu, Japan

Chem. Commun., 2013,49, 179-180

DOI: 10.1039/C2CC36873K
Received 21 Sep 2012, Accepted 09 Nov 2012
First published online 09 Nov 2012

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A dye-sensitized solar cell (DSSC) fabricated by using a Mg²⁺-doped anatase-TiO₂ electrode with an alkoxysilyl dye and a Br₃⁻/Br⁻ electrolyte solution exhibited successfully a remarkably high open-circuit photovoltage over 1.2 V, demonstrating a new possibility of DSSCs as practical photovoltaic devices.

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Kenji Kakiage
Toru Tokutome
Shinji Iwamoto
Toru Kyomen
Minoru Hanaya

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Chemical Communications

Fabrication of a dye-sensitized solar cell containing a Mg-doped TiO₂ electrode and a Br₃⁻/Br⁻ redox mediator with a high open-circuit photovoltage of 1.21 V

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Fabrication of a dye-sensitized solar cell containing a Mg-doped TiO2 electrode and a Br3−/Br− redox mediator with a high open-circuit photovoltage of 1.21 V

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Fabrication of a dye-sensitized solar cell containing a Mg-doped TiO₂ electrode and a Br₃⁻/Br⁻ redox mediator with a high open-circuit photovoltage of 1.21 V