Issue 19, 2013
From the journal:

Chemical Communications

Catalytic “triangles”: binding of iron in task-specific ionic liquids†

Denis Prodius,*ab   Fliur Macaev,b   Eugenia Stingaci,b   Vsevolod Pogrebnoi,b   Valeriu Mereacre,a   Ghenadie Novitchi,bc   George E. Kostakis,d   Christopher E. Ansona  and  Annie K. Powell*ad  

* Corresponding authors

a Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76128 Karlsruhe, Germany
E-mail: annie.powell@kit.edu
Fax: +49 721-608-48142
Tel: +49 721-608-42135

b Institute of Chemistry of the Academy of Sciences of Moldova, Academiei str. 3, MD-2028 Chisinau, Moldova
E-mail: denis.prodius@kit.edu
Fax: +373 22 739722
Tel: +373 22 739954

c Laboratoire National des Champs Magnétiques Intenses, CNRS UPR 3228, 25 Rue des Martyrs, Grenoble, France

d Institute of Nanotechnology, Karlsruhe Institute of Technology, Hermann-von-Helmholtz Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Abstract

A new class of task-specific ionic liquids (ILs) which contain septuply positively charged {Fe3IIIO(RCOO)6L3}7+ triangles has been synthesized and structurally characterized. Such metal-containing ILs can be repeatedly used as alternative catalysts in the synthesis of 2-pyrrolo-3′-yloxindole or the condensation of indoles with various aldehydes.

Graphical abstract: Catalytic “triangles”: binding of iron in task-specific ionic liquids

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Article information

DOI
https://doi.org/10.1039/C2CC36741F
Article type
Communication
Submitted
16 Sep 2012
Accepted
19 Oct 2012
First published
22 Oct 2012

Chem. Commun., 2013,49, 1915-1917

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Catalytic “triangles”: binding of iron in task-specific ionic liquids

D. Prodius, F. Macaev, E. Stingaci, V. Pogrebnoi, V. Mereacre, G. Novitchi, G. E. Kostakis, C. E. Anson and A. K. Powell, Chem. Commun., 2013, 49, 1915 DOI: 10.1039/C2CC36741F

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