Cs4Mo5P2O22: a first Strandberg-type POM with 1D straight chains of polymerized [Mo5P2O23]6− units and moderate second harmonic generation response

Ying Wang; Shilie Pan; Hongwei Yu; Xin Su; Min Zhang; Fangfang Zhang; Jian Han

doi:10.1039/C2CC36354B

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Cs₄Mo₅P₂O₂₂: a first Strandberg-type POM with 1D straight chains of polymerized [Mo₅P₂O₂₃]⁶⁻ units and moderate second harmonic generation response†

Ying Wang,^ab Shilie Pan,*^a Hongwei Yu,^ab Xin Su,^a Min Zhang,^a Fangfang Zhang^a and Jian Han*^a

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* Corresponding authors

^a Xinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences, 40-1 South Beijing Road, Urumqi 830011, China
E-mail: slpan@ms.xjb.ac.cn
Tel: +86-991-3674558

^b University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

A noncentrosymmetric chiral Strandberg-type polyoxometalate based material, Cs₄Mo₅P₂O₂₂, that contains unusual one dimensional chains constructed from [Mo₅P₂O₂₃]⁶⁻ units has been reported. Cs₄Mo₅P₂O₂₂ shows a moderate SHG response, and is phase-matchable.

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Article information

DOI: https://doi.org/10.1039/C2CC36354B
Article type: Communication
Submitted: 31 Aug 2012
Accepted: 24 Oct 2012
First published: 25 Oct 2012

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Chem. Commun., 2013,49, 306-308

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Cs₄Mo₅P₂O₂₂: a first Strandberg-type POM with 1D straight chains of polymerized [Mo₅P₂O₂₃]⁶⁻ units and moderate second harmonic generation response

Y. Wang, S. Pan, H. Yu, X. Su, M. Zhang, F. Zhang and J. Han, Chem. Commun., 2013, 49, 306 DOI: 10.1039/C2CC36354B

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