The synthesis of a bromopropyl-substituted NHC–Pd(II) complex, which can undergo exemplary and versatile 2nd and 3rd generation post-modifications easily affording 7 new functionalised NHC complexes, is demonstrated.
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Highly modular access to functionalised metal-carbenes via post-modifications of a single bromoalkyl-substituted NHC–Pd(II) complex
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Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore
E-mail: chmhhv@nus.edu.sg ;
Fax: +65 6779 1691 ;
Tel: +65 6516 2670
E-mail: chmhhv@nus.edu.sg ;
Fax: +65 6779 1691 ;
Tel: +65 6516 2670
Chem. Commun., 2013,49, 4244-4246
DOI: 10.1039/C2CC33789D
Received 26 May 2012, Accepted 19 Jul 2012
First published online 19 Jul 2012
This article is part of themed collection:
Emerging Investigators 2013
Chemical Communications
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