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Issue 40, 2012
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A surfactant-assisted unimolecular platform for multicolor emissions

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Abstract

We present here a simple molecular assembly approach to multicolor emissions based on a unimolecular platform of a terthiophene-containing amphiphile TTC4L. The amphiphiles self-assemble into vesicles in solution which exhibit a blue emission. Upon controlling the distance between the fluorescent terthiophene groups by transformation of the self-assembly of TTC4L molecules into their co-assembly with surfactants, the color of the emissions can be continuously tailored which covers most of the visible region. Since the multi-colors were obtained without any structural modification on the fluorescent molecules, we have demonstrated a real unimolecular platform for fabricating multicolor emissions. In contrast, only dual emissions can be obtained from TTC4L using host–guest chemistry. As a simple approach of ‘tunable emissions’, this surfactant-assisted unimolecular platform opens a new vista for the application of molecular assemblies in advanced light emitting materials.

Graphical abstract: A surfactant-assisted unimolecular platform for multicolor emissions

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Publication details

The article was received on 20 Jul 2012, accepted on 09 Aug 2012 and first published on 31 Aug 2012


Article type: Paper
DOI: 10.1039/C2SM26678D
Citation: Soft Matter, 2012,8, 10472-10478
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    A surfactant-assisted unimolecular platform for multicolor emissions

    L. Zhao, X. Cheng, Y. Ding, Y. Yan and J. Huang, Soft Matter, 2012, 8, 10472
    DOI: 10.1039/C2SM26678D

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