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Issue 5, 2012
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Metallosupramolecular amphiphilic π-systems

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Abstract

Metallosupramolecular π-amphiphiles are emerging as a new class of adaptive materials that combine the ability of π-conjugated systems to self-assemble in a “programmed” fashion and the versatile coordination geometry and well-known optical, electronic and magnetic properties of metal ions. In particular, their aqueous self-assembly is expected to yield a wide variety of supramolecular structures of unprecedented complexity through multiple noncovalent interactions. This approach provides access to smart materials with functionalities that can be controlled by environmental changes such as pH or the addition of metal ions. A wide range of applications can be envisaged in fields as diverse as catalysis, biomedicine or materials science.

Graphical abstract: Metallosupramolecular amphiphilic π-systems

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Publication details

The article was received on 22 Dec 2011, accepted on 15 Jan 2012 and first published on 18 Jan 2012


Article type: Minireview
DOI: 10.1039/C2SC01101H
Citation: Chem. Sci., 2012,3, 1395-1398
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    Metallosupramolecular amphiphilic π-systems

    M. J. Mayoral Muñoz and G. Fernández, Chem. Sci., 2012, 3, 1395
    DOI: 10.1039/C2SC01101H

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