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Issue 4, 2012
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“Push effect” of sulfur coordination: promoting the breaking of C(sp2)–I bond by pincer thioimido-Pd(II) complexes

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Abstract

Aryliodo bond cleavage by pincer thioimido-Pd(II) complex was demonstrated by in situ IR and X-ray analysis. Stoichiometric reactions indicated the crucial role of substrate sulfur coordination to the Pd centre. Possible mechanisms were proposed and catalytic reaction was developed.

Graphical abstract: “Push effect” of sulfur coordination: promoting the breaking of C(sp2)–I bond by pincer thioimido-Pd(ii) complexes

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Publication details

The article was received on 07 Nov 2011, accepted on 03 Jan 2012 and first published on 05 Jan 2012


Article type: Edge Article
DOI: 10.1039/C2SC00888B
Citation: Chem. Sci., 2012,3, 1211-1214
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    “Push effect” of sulfur coordination: promoting the breaking of C(sp2)–I bond by pincer thioimido-Pd(II) complexes

    J. Liu, Y. Deng, C. Lin and A. Lei, Chem. Sci., 2012, 3, 1211
    DOI: 10.1039/C2SC00888B

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