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Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin, China
; Fax: +86-22-23508662
; Tel: +86-22-23508662
RSC Adv., 2012,2, 5178-5184
05 Mar 2012,
07 Mar 2012
First published online
08 Mar 2012
Mesoporous MCM-41 was functionalized using magnesium nitrate hexahydrate (denoted as MM). The adsorption behavior of Cd2+ on functionalized MCM-41 was investigated systematically. The adsorption isotherms of MM for Cd(II) could be described by the Langmuir isotherm model. The adsorption rates were very high and agreed well with pseudo second-order kinetics. The modified MCM-41 adsorbent displayed excellent Cd2+ adsorption efficiency (210.96 mg g−1) and the residual concentration of Cd2+ achieved was in line with drinking water quality standards. The regeneration capacity maintained 99% performance when the initial solution concentration was 5 mg L−1 (5000 ppb) at the eighth cycle, meeting the safe regulatory discharge standard for the first time. Furthermore, regeneration by an ultrasonic cleaning method to remove residual surface Cd2+ can reduce both the cost of traditional desorption agents and damage to the structure of the adsorbent. Therefore, the adsorbent MM has potential as a promising application in the field of water pollution control.
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