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Max-Planck-Institut für Bioanorganische Chemie, Stifstrasse 34-36, D-45470 Mülheim an der Ruhr, Germany
; Fax: +49 (0)208 306 3591
; Tel: +49 (0)208 306 3671
Dipartimento di Fisica, Università degli Studi di Parma, and NEST, Istituto Nanoscienze-CNR, viale delle Scienze 7A, 43124 Parma, Italy
; Fax: +39 0521 905223
; Tel: +39 0521 905208
Photochem. Photobiol. Sci., 2012,11, 620-622
26 Oct 2011,
23 Feb 2012
First published online
12 Mar 2012
A photoactivatable caged cyanide, 1-(2-nitrophenyl)ethyl (NPE) cyanide, was synthesized, which upon irradiation in the near UV releases cyanide. It is demonstrated that the compound can be used to induce formation of the FeIII–CN− complex in the heme protein nitrophorin 4 from Rhodnius prolixus.
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Photochemical & Photobiological Sciences
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