A caged cyanide

Markus Knipp; Johanna J. Taing; Chunmao He; Cristiano Viappiani

doi:10.1039/C2PP05359D

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Photochemical & Photobiological Sciences

Issue 4, 2012

A society-owned journal publishing high quality research on all aspects of photochemistry and photobiology.

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A caged cyanide

Markus Knipp,*^a Johanna J. Taing,^a Chunmao He^a and Cristiano Viappiani*^b

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Max-Planck-Institut für Bioanorganische Chemie, Stifstrasse 34-36, D-45470 Mülheim an der Ruhr, Germany
E-mail: mknipp@mpi-muelheim.mpg.de ;
Fax: +49 (0)208 306 3591 ;
Tel: +49 (0)208 306 3671

Dipartimento di Fisica, Università degli Studi di Parma, and NEST, Istituto Nanoscienze-CNR, viale delle Scienze 7A, 43124 Parma, Italy
E-mail: cristiano.viappiani@fis.unipr.it ;
Fax: +39 0521 905223 ;
Tel: +39 0521 905208

Photochem. Photobiol. Sci., 2012,11, 620-622

DOI: 10.1039/C2PP05359D
Received 26 Oct 2011, Accepted 23 Feb 2012
First published online 12 Mar 2012

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A photoactivatable caged cyanide, 1-(2-nitrophenyl)ethyl (NPE) cyanide, was synthesized, which upon irradiation in the near UV releases cyanide. It is demonstrated that the compound can be used to induce formation of the Fe^III–CN⁻ complex in the heme protein nitrophorin 4 from Rhodnius prolixus.

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