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Issue 34, 2012
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Insights into the elementary steps in Negishi coupling through kinetic investigations

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Abstract

The Negishi coupling has been widely applied in organic synthesis, while relevant mechanistic studies are relatively rare. To obtain an understanding of the fundamental steps in the Negishi coupling, oxidative addition, transmetalation and reductive elimination, the kinetic investigation has served as one of the most important strategies. In this review, insights into the elementary steps in the Negishi coupling through kinetic investigations are summarized.

Graphical abstract: Insights into the elementary steps in Negishi coupling through kinetic investigations

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Publication details

The article was received on 31 Mar 2012, accepted on 15 Jun 2012 and first published on 18 Jun 2012


Article type: Perspective
DOI: 10.1039/C2OB25650A
Citation: Org. Biomol. Chem., 2012,10, 6817-6825
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    Insights into the elementary steps in Negishi coupling through kinetic investigations

    L. Jin and A. Lei, Org. Biomol. Chem., 2012, 10, 6817
    DOI: 10.1039/C2OB25650A

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