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Issue 20, 2012
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Simple chiral sulfonamide primary amine catalysed highly enantioselective Michael addition of malonates to enones

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Abstract

A chiral sulfonamide primary amine-organocatalysed, highly enantioselective Michael addition of malonates to enones has been developed. This reaction afforded the corresponding products in excellent yields (up to 99%) and excellent enantioselectivity (up to 99% ee).

Graphical abstract: Simple chiral sulfonamide primary amine catalysed highly enantioselective Michael addition of malonates to enones

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Publication details

The article was received on 29 Dec 2011, accepted on 22 Mar 2012 and first published on 23 Mar 2012


Article type: Paper
DOI: 10.1039/C2OB07191F
Citation: Org. Biomol. Chem., 2012,10, 4116-4123
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    Simple chiral sulfonamide primary amine catalysed highly enantioselective Michael addition of malonates to enones

    C. Luo, Y. Jin and D. Du, Org. Biomol. Chem., 2012, 10, 4116
    DOI: 10.1039/C2OB07191F

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