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Issue 12, 2012
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Direct O-glycosidation of resin bound thioglycosides

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Abstract

The application of the safety-catch linker concept to solid-phase glycoconjugate synthesis is described. The process allows for direct conjugation of resin bound glycans to complex aglycones during cleavage. Large excesses of either coupling partner are not required, and even very hindered alcohols serve as acceptors in the reaction.

Graphical abstract: Direct O-glycosidation of resin bound thioglycosides

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Publication details

The article was received on 08 Nov 2011, accepted on 19 Dec 2011 and first published on 20 Dec 2011


Article type: Communication
DOI: 10.1039/C2OB06883D
Citation: Org. Biomol. Chem., 2012,10, 2373-2376
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    Direct O-glycosidation of resin bound thioglycosides

    S. H. Nguyen, A. H. Trotta, J. Cao, T. J. Straub and C. S. Bennett, Org. Biomol. Chem., 2012, 10, 2373
    DOI: 10.1039/C2OB06883D

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