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Issue 9, 2012
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Colour-responsive fluorescent oxy radical sensors

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Abstract

A series of fluorene-fused benzoquinones (Q1–Q5) were prepared by thermolysis of 4-fluorenyl-4-hydroxycyclobutenones. Red fluorescence observed for Q2 is switched by reduction to blue fluorescence by formation of the hydroquinone. Reaction with hydrogen peroxide restores the original fluorescence colour. The potential use of compound Q2 as a reactive oxygen species detector is discussed.

Graphical abstract: Colour-responsive fluorescent oxy radical sensors

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Publication details

The article was received on 31 Oct 2011, accepted on 05 Dec 2011 and first published on 07 Dec 2011


Article type: Paper
DOI: 10.1039/C2OB06825G
Citation: Org. Biomol. Chem., 2012,10, 1775-1784
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    Colour-responsive fluorescent oxy radical sensors

    B. Yucel, B. Sanli, H. Akbulut, S. Ozbey and A. C. Benniston, Org. Biomol. Chem., 2012, 10, 1775
    DOI: 10.1039/C2OB06825G

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