Benzimidazole-based anion receptors: tautomeric switching and selectivity

Philip A. Gale; Jennifer R. Hiscock; Noémie Lalaoui; Mark E. Light; Neil J. Wells; Marco Wenzel

doi:10.1039/C1OB06800H

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Benzimidazole-based anion receptors: tautomeric switching and selectivity

Philip A. Gale , Jennifer R. Hiscock , Noémie Lalaoui , Mark E. Light , Neil J. Wells and Marco Wenzel

Org. Biomol. Chem., 2012, Advance Article

DOI: 10.1039/C1OB06800H
Received 26 Oct 2011, Accepted 17 Nov 2011
First published on the web 17 Nov 2011

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Tautomeric switching is observed in a series of benzimidazole-based anion receptors upon addition of basic anions. An N-methylbenzimidazole based receptor selectively interacts with dihydrogen phosphate over a variety of other putative anionic guests via a combination of donated and accepted hydrogen bonds.

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Articles By

Philip A. Gale
Jennifer R. Hiscock
Noémie Lalaoui
Mark E. Light
Neil J. Wells
Marco Wenzel

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Organic & Biomolecular Chemistry

Benzimidazole-based anion receptors: tautomeric switching and selectivity

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