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Issue 1, 2012
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Synthesis of α,β-unsaturated γ-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl α-arylenamines and acrylates

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Abstract

Ruthenium-catalyzed highly selective codimerization of N-acetyl α-arylenamines with ethyl acrylates is reported. This codimerization reaction provides a new efficient method for the synthesis of α,β-unsaturated γ-amino esters with a quaternary center.

Graphical abstract: Synthesis of α,β-unsaturated γ-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl α-arylenamines and acrylates

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Publication details

The article was received on 18 Aug 2011, accepted on 09 Sep 2011 and first published on 09 Sep 2011


Article type: Communication
DOI: 10.1039/C1OB06412F
Citation: Org. Biomol. Chem., 2012,10, 43-45
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    Synthesis of α,β-unsaturated γ-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl α-arylenamines and acrylates

    Q. Wang, J. Xie, L. Guo and Q. Zhou, Org. Biomol. Chem., 2012, 10, 43
    DOI: 10.1039/C1OB06412F

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