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Issue 9, 2013
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Migration of methylethynyl group in a long-lived carbocation

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Abstract

Degenerate 1,2-shift of methylethynyl group in long-lived 9,10-dimethyl-9-methylethynyl-phenanthrenium ion has been detected by NMR. This is the first example of ethynyl migration in a long-lived carbocation.

Graphical abstract: Migration of methylethynyl group in a long-lived carbocation

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Publication details

The article was received on 13 Nov 2012, accepted on 02 Jan 2013 and first published on 03 Jan 2013


Article type: Paper
DOI: 10.1039/C2OB27208C
Citation: Org. Biomol. Chem., 2013,11, 1498-1501
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    Migration of methylethynyl group in a long-lived carbocation

    G. E. Salnikov, A. M. Genaev, V. A. Bushmelev and V. G. Shubin, Org. Biomol. Chem., 2013, 11, 1498
    DOI: 10.1039/C2OB27208C

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