Synthesis and properties of squaraine-modified DNA

Larysa I. Markova; Vladimir L. Malinovskii; Leonid D. Patsenker; Robert Häner

doi:10.1039/C2OB26787J

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Organic & Biomolecular Chemistry

Issue 45, 2012

The international home of synthetic, physical and biomolecular organic chemistry.

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Synthesis and properties of squaraine-modified DNA

Larysa I. Markova,^a^b Vladimir L. Malinovskii,^a Leonid D. Patsenker^b and Robert Häner*^a

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Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, CH-3012 Bern, Switzerland
E-mail: robert.haener@ioc.unibe.ch ;
Tel: (+)41 31 631 4382

Department of Organic Luminophores and Dyes, State Scientific Institution “Institute for Single Crystals” of the National Academy of Sciences of Ukraine, 60, Lenin Ave., Kharkiv 61001, Ukraine
E-mail: patsenker@isc.kharkov.com ;
Fax: +38 (057) 340-02-73 ;
Tel: +38 (057) 341-02-72

Org. Biomol. Chem., 2012,10, 8944-8947

DOI: 10.1039/C2OB26787J
Received 11 Sep 2012, Accepted 02 Oct 2012
First published online 02 Oct 2012

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Abstract
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The incorporation of squaraines into DNA via the phosphoramidite approach is described. High molar absorptivity, environment-sensitive fluorescence properties and intense CD effects render squaraines valuable building blocks for DNA-based optical probes and nanostructures.

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