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Key Laboratory of Natural Medicine and Immuno-Engineering of Henan Province, Henan University, Jinming Campus, Kaifeng, PR China
; Fax: +86-378-286-4665
; Tel: +86-378-286-4665
Org. Biomol. Chem., 2012,10, 8975-8984
02 Aug 2012,
28 Aug 2012
First published online
29 Aug 2012
The [3 + 2] cycloaddition of arynes with 3-oxidopyridinium species is examined using the Kobayashi benzyne precursor. The reaction affords a bicyclo[3.2.1] skeleton under mild conditions. A [7 + 2] cycloaddition mode with a subsequent pyridine ring-opening event has also been observed.
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Organic & Biomolecular Chemistry
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