In the presence of an oxidant, sodium iodide is converted into hypoiodous acid which effects the rearrangement of tertiary propargylic alcohols to α-iodoenones in good yields.
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Hypoiodous acid initiated rearrangement of tertiary propargylic alcohols to α-iodoenones
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Department of Chemical and Biological Sciences, University of Huddersfield, Huddersfield HD1 3DH, UK
E-mail: w.j.moran@hud.ac.uk ;
Fax: +44 (0)1484 472182 ;
Tel: +44 (0)1484 473741
E-mail: w.j.moran@hud.ac.uk ;
Fax: +44 (0)1484 472182 ;
Tel: +44 (0)1484 473741
Org. Biomol. Chem., 2012,10, 8590-8592
DOI: 10.1039/C2OB26360B
Received 07 Jun 2012, Accepted 02 Oct 2012
First published online 03 Oct 2012
Organic & Biomolecular Chemistry
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