The total synthesis of noricumazole B, a secondary metabolite from myxobacteria, was achieved. It established the glycan moiety to be D-α-arabinoside.
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Total synthesis of noricumazole B establishes D-arabinose as glycan unit
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a
Institut für Organische Chemie and Biomolekulares Wirkstoffzentrum (BMWZ), Leibniz Universität Hannover, Schneiderberg 1b, 30167 Hannover, Germany
E-mail: andreas.kirschning@oci.uni-hannover.de ;
Fax: +49 (0)511-7623011 ;
Tel: +49 (0)511-7624614
E-mail: andreas.kirschning@oci.uni-hannover.de ;
Fax: +49 (0)511-7623011 ;
Tel: +49 (0)511-7624614
b
Helmholtz Zentrum für Infektionsforschung (HZI), Inhoffenstrasse 7, 38124 Braunschweig, Germany
Org. Biomol. Chem., 2012,10, 8298-8307
DOI: 10.1039/C2OB26256H
Received 02 Jul 2012, Accepted 21 Aug 2012
First published online 21 Aug 2012
Organic & Biomolecular Chemistry
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