Conformational modulation of Ant–Pro oligomers using chirality alteration of proline residues

Sangram S. Kale; Amol S. Kotmale; Achintya Kumar Dutta; Sourav Pal; P. R. Rajamohanan; Gangadhar J. Sanjayan

doi:10.1039/C2OB26132D

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Organic & Biomolecular Chemistry

Issue 42, 2012

The international home of synthetic, physical and biomolecular organic chemistry.

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Conformational modulation of Ant–Pro oligomers using chirality alteration of proline residues

Sangram S. Kale,^a Amol S. Kotmale,^b Achintya Kumar Dutta,^c Sourav Pal,^c P. R. Rajamohanan^b and Gangadhar J. Sanjayan*^a

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Division of Organic Chemistry, National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411 008, India
E-mail: gj.sanjayan@ncl.res.in ;
Fax: +91-020-2590-2629 ;
Tel: +91-020-2590-2082

Central NMR Facility, National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411 008, India

Division of Physical Chemistry, National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411 008, India

Org. Biomol. Chem., 2012,10, 8426-8433

DOI: 10.1039/C2OB26132D
Received 13 Jun 2012, Accepted 10 Sep 2012
First published online 11 Sep 2012

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Structural modulation of Ant–Pro (anthranilic acid–proline) oligomers has been carried out by chirality alteration of the proline residues. The results suggest that the chirality altered oligomers show well-defined helical conformation featuring nine-membered hydrogen bonding interactions – without compromising conformational rigidity.

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Sangram S. Kale
Amol S. Kotmale
Achintya Kumar Dutta
Sourav Pal
P. R. Rajamohanan
Gangadhar J. Sanjayan

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Conformational modulation of Ant–Pro oligomers using chirality alteration of proline residues

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