We have demonstrated that mononuclear Zn(II)–dipicolylamine (DPA) complexes with an auxiliary ligand can fluorescently discriminate pyrophosphate over ATP with as high selectivity as the known fast responding dinuclear bis(ZnDPA) complexes.
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Studies on acedan-based mononuclear zinc complexes toward selective fluorescent probes for pyrophosphate
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a
Department of Chemistry and Center for Electro-Photo Behaviors in Advance Molecular Systems, San 31 Hyoja-dong, Pohang, Republic of Korea
E-mail: ahn@postech.ac.kr ;
Fax: +82542795877 ;
Tel: +82542792105
E-mail: ahn@postech.ac.kr ;
Fax: +82542795877 ;
Tel: +82542792105
b
School of Environmental Science and Engineering, POSTECH, San 31 Hyoja-dong, Pohang, Republic of Korea
Org. Biomol. Chem., 2012,10, 8410-8417
DOI: 10.1039/C2OB26000J
Received 23 May 2012, Accepted 11 Sep 2012
First published online 11 Sep 2012
Organic & Biomolecular Chemistry
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