An efficient allylic amination of Morita–Baylis–Hillman acetates with simple aromatic amines provided good yields with excellent α-regioselectivity (up to exclusive α-product) under the catalysis of Pd2(dba)3/ferrocene-type diphosphine ligand.
The international home of synthetic, physical and biomolecular organic chemistry.
Impact Factor
3.696
48 Issues per Year
Indexed in MEDLINE
Paper
Palladium-catalyzed α-regioselective allylic amination of Morita–Baylis–Hillman acetates with simple aromatic amines
Show Affiliations
Hide Affiliations
*
Corresponding authors
a
Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail: lliu@iccas.ac.cn ;
Fax: +86 010 6255 4449 ;
Tel: +86 010 6255 4614
E-mail: lliu@iccas.ac.cn ;
Fax: +86 010 6255 4449 ;
Tel: +86 010 6255 4614
b
Graduate School of Chinese Academy of Sciences, Beijing 100049, China
Org. Biomol. Chem., 2012,10, 6908-6913
DOI: 10.1039/C2OB25976A
Received 21 May 2012, Accepted 26 Jun 2012
First published online 27 Jun 2012
Organic & Biomolecular Chemistry
- Information Point
Supplementary Info
-
Supplementary information
PDF (2839K)