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Issue 42, 2012
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Chiral imidate–ferrocenylphosphanes: synthesis and application as P,N-ligands in iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins

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Abstract

A small library of chiral imidate–ferrocenylphosphane ligands was efficiently synthesized (8 examples) and evaluated in the iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins. These catalysts perform very well in a range of examples (yields and ee's up to 100%).

Graphical abstract: Chiral imidate–ferrocenylphosphanes: synthesis and application as P,N-ligands in iridium(i)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins

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Publication details

The article was received on 07 May 2012, accepted on 08 Aug 2012 and first published on 09 Aug 2012


Article type: Paper
DOI: 10.1039/C2OB25871D
Citation: Org. Biomol. Chem., 2012,10, 8539-8550
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    Chiral imidate–ferrocenylphosphanes: synthesis and application as P,N-ligands in iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins

    K. Bert, T. Noël, W. Kimpe, J. L. Goeman and J. Van der Eycken, Org. Biomol. Chem., 2012, 10, 8539
    DOI: 10.1039/C2OB25871D

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