Pentapodal ω-functional derivatives of corannulene have been synthesized from sym-pentachlorocorannulene by iron-catalyzed aryl–alkyl cross coupling reactions. Click chemistry gives access to pentapods with bioconjugate appendages.
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Sym-(CH2X)5-corannulenes: molecular pentapods displaying functional group and bioconjugate appendages
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Organic Chemistry Institute, University of Zurich, Winterthurerstrasse 190, 8057 Zurich, Switzerland
E-mail: jss@oci.uzh.ch ;
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Tel: +41 44 635 4281
E-mail: jss@oci.uzh.ch ;
Fax: +41 44 635 6888 ;
Tel: +41 44 635 4281
Org. Biomol. Chem., 2012,10, 5799-5802
DOI: 10.1039/C2OB25503K
Received 08 Mar 2012, Accepted 17 Apr 2012
First published online 18 Apr 2012
This article is part of themed collection:
Organic & Biomolecular Chemistry 10th Anniversary
Organic & Biomolecular Chemistry
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