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Issue 24, 2012
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First total synthesis of (+)-indicanone

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Abstract

The first total synthesis of the guaiane-type sesquiterpene, (+)-indicanone (1), isolated from the root of Wikstroemia indica, was accomplished based on the rhodium(I)-catalyzed Pauson–Khand-type reaction of the allenyne derivative, which was derived from (+)-limonene. This total synthesis unambiguously confirmed the complete structure of (+)-indicanone involving its absolute stereochemistry.

Graphical abstract: First total synthesis of (+)-indicanone

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Publication details

The article was received on 08 Mar 2012, accepted on 25 Apr 2012 and first published on 25 Apr 2012


Article type: Paper
DOI: 10.1039/C2OB25500F
Citation: Org. Biomol. Chem., 2012,10, 4747-4751
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    First total synthesis of (+)-indicanone

    Y. Hayashi, K. Ogawa, F. Inagaki and C. Mukai, Org. Biomol. Chem., 2012, 10, 4747
    DOI: 10.1039/C2OB25500F

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