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TOS. Lab. of Ural Federal University named after first President of Russia B. N. Eltsin, 19 Mira Str., 620002 Yekaterinburg, Russia
; Fax: +7 343-3745483
; Tel: +7 343 3754135
I. Ya. Postovsky Institute of Organic Synthesis, Ural branch of Russian Academy of Science, Yekaterinburg, Russia
Novel self-condensation of 3-(azol-5-yl)-1,1-dimethylenamines has been found to form new C–C bonds leading to 2,4-(1,2,3-triazole-1,2,3-thiadiazole-3-phenylisothiazole)-(1E,3Z)-5-yl-butadiene-1-amines. The discovered reaction represents a new example of C–H functionalization in unsaturated systems and can serve an efficient synthetic approach to rational design of new 2,4-(diazole-5-yl)-dieneamines.
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Organic & Biomolecular Chemistry
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