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Facile air-oxidation of large aromatic hydrocarbon bay regions to bay region quinones: predicted oxygen-sensitivity of hydrogen-terminated carbon nanotubes
Merkert Chemistry Center, Department of Chemistry, Boston College, Chestnut Hill, USA
E-mail: lawrence.scott@bc.edu
; Fax: +617-552-6454
; Tel: +617-552-8024
Org. Biomol. Chem., 2012,10, 5747-5749
DOI:
10.1039/C2OB25208B
Received
27 Jan 2012,
Accepted
08 Feb 2012
First published online
27 Feb 2012
Dimesitylbisanthene (1) oxidizes to the corresponding bay region quinone (2) on standing in solutions exposed to air and ambient light. It is anticipated that hydrogen-terminated carbon nanotubes with bay regions on the rim are likely to exhibit even greater sensitivity toward air oxidation.
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Organic & Biomolecular Chemistry
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