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Issue 13, 2012
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Asymmetric catalytic Mannich-type reaction of hydrazones with difluoroenoxysilanes using imidazoline-anchored phosphine ligand–zinc(II) complexes

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Abstract

Asymmetric Mannich-type reaction of hydrazones with difluoroenoxysilanes using chiral zinc(II)–imidazoline–phosphine complexes as catalysts have been established, giving the corresponding adducts in good to excellent enantioselectivity and chemical yields under mild conditions.

Graphical abstract: Asymmetric catalytic Mannich-type reaction of hydrazones with difluoroenoxysilanes using imidazoline-anchored phosphine ligand–zinc(ii) complexes

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Publication details

The article was received on 01 Dec 2011, accepted on 06 Jan 2012 and first published on 09 Jan 2012


Article type: Communication
DOI: 10.1039/C2OB07022G
Citation: Org. Biomol. Chem., 2012,10, 2509-2513
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    Asymmetric catalytic Mannich-type reaction of hydrazones with difluoroenoxysilanes using imidazoline-anchored phosphine ligand–zinc(II) complexes

    Z. Yuan, L. Mei, Y. Wei, M. Shi, P. V. Kattamuri, P. McDowell and G. Li, Org. Biomol. Chem., 2012, 10, 2509
    DOI: 10.1039/C2OB07022G

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