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State Key laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, P. R. China
; Fax: (+86) 21-6416-6128 (+1) 806-742-3015
Department of Chemistry and Biochemistry, Texas Tech University, Lubbock
; Fax: (+1) 806-742-3015
Org. Biomol. Chem., 2012,10, 2509-2513
01 Dec 2011,
06 Jan 2012
First published online
09 Jan 2012
Asymmetric Mannich-type reaction of hydrazones with difluoroenoxysilanes using chiral zinc(II)–imidazoline–phosphine complexes as catalysts have been established, giving the corresponding adducts in good to excellent enantioselectivity and chemical yields under mild conditions.
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Organic & Biomolecular Chemistry
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