Jump to main content
Jump to site search

Issue 11, 2012
Previous Article Next Article

Methane storage in molecular nanostructures

Author affiliations

Abstract

We survey various molecular structures which have been proposed as possible nanocontainers for methane storage. These are molecular structures that have been investigated through either experiments, molecular dynamics simulations or mathematical modelling. Computational simulation and mathematical modelling play an important role in predicting and verifying experimental outcomes, but both have their limitations. Even though recent advances have greatly improved computations, due to the large number of atoms and force field calculations involved, computational simulations can still be time consuming as compared to an instantaneous mathematical modelling approach. On the other hand, underlying an ideal mathematical model, there are many assumptions and approximations, but such modelling often reveals the key physical parameters and optimal configurations. Here, we review methane adsorption for three conventional nanostructures, namely graphite, single and multi-walled carbon nanotubes, and nanotube bundles (including interstitial and groove sites), and we survey methane adsorption in other molecular structures including metal organic frameworks. We also include an examination of minimum binding energies, equilibrium distances, gravimetric and volumetric uptakes, volume available for adsorption, as well as the effects of temperature and pressure on the adsorption of methane onto these molecular structures.

Graphical abstract: Methane storage in molecular nanostructures

Back to tab navigation
Please wait while Download options loads

Publication details

The article was received on 06 Jan 2012, accepted on 27 Mar 2012 and first published on 02 Apr 2012


Article type: Review Article
DOI: 10.1039/C2NR00042C
Citation: Nanoscale, 2012,4, 3295-3307
  •   Request permissions

    Methane storage in molecular nanostructures

    O. O. Adisa, B. J. Cox and J. M. Hill, Nanoscale, 2012, 4, 3295
    DOI: 10.1039/C2NR00042C

Search articles by author