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Issue 7, 2012
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Aryl carbinols as nerve agent probes. Influence of the conjugation on the sensing properties

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Abstract

Two new aryl carbinols (1 and 3) have been synthesised and characterised and their ability as OFF–ON probes for the chromogenic detection of the nerve agent simulant in acetonitrile has been tested. In addition compound 2 has been also studied. The carbinols suffered a phosphorylation reaction followed by an elimination process giving rise to the corresponding carbocations. This transformation of the carbinol into the carbocation is responsible for a significant color change.

Graphical abstract: Aryl carbinols as nerve agent probes. Influence of the conjugation on the sensing properties

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Publication details

The article was received on 14 Feb 2012, accepted on 04 Apr 2012, published on 13 Apr 2012 and first published online on 13 Apr 2012


Article type: Paper
DOI: 10.1039/C2NJ40104E
Citation: New J. Chem., 2012,36, 1485-1489
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    Aryl carbinols as nerve agent probes. Influence of the conjugation on the sensing properties

    S. Royo, R. Gotor, A. M. Costero, M. Parra, S. Gil, R. Martínez-Máñez and F. Sancenón, New J. Chem., 2012, 36, 1485
    DOI: 10.1039/C2NJ40104E

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