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Issue 5, 2012
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A tridentate Ni pincer for aqueous electrocatalytic hydrogen production

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Abstract

A NiII complex with a redox-active pincer ligand reduces protons at a low overpotential in aqueous acidic conditions. A combined experimental and computational study provides mechanistic insights into a putative catalytic cycle.

Graphical abstract: A tridentate Ni pincer for aqueous electrocatalytic hydrogen production

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Publication details

The article was received on 25 Oct 2011, accepted on 29 Feb 2012, published on 19 Mar 2012 and first published online on 19 Mar 2012


Article type: Letter
DOI: 10.1039/C2NJ20912H
Citation: New J. Chem., 2012,36, 1149-1152
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    A tridentate Ni pincer for aqueous electrocatalytic hydrogen production

    O. R. Luca, S. J. Konezny, J. D. Blakemore, D. M. Colosi, S. Saha, G. W. Brudvig, V. S. Batista and R. H. Crabtree, New J. Chem., 2012, 36, 1149
    DOI: 10.1039/C2NJ20912H

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