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Issue 34, 2012
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Crystal chemistry of Na insertion/deinsertion in FePO4–NaFePO4

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Abstract

In this paper we examine the mechanism of Na insertion and extraction in the FePO4–NaFePO4 system. Chemical preparation of the intermediate Na1−xFePO4 phase has revealed the existence of a range of stable compositions with different Na+/vacancy arrangements. The mechano-chemical aspects of the charge and discharge reactions are also discussed.

Graphical abstract: Crystal chemistry of Na insertion/deinsertion in FePO4–NaFePO4

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Publication details

The article was received on 06 Jun 2012, accepted on 09 Jul 2012 and first published on 10 Jul 2012


Article type: Communication
DOI: 10.1039/C2JM33639A
Citation: J. Mater. Chem., 2012,22, 17421-17423
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    Crystal chemistry of Na insertion/deinsertion in FePO4–NaFePO4

    M. Casas-Cabanas, V. V. Roddatis, D. Saurel, P. Kubiak, J. Carretero-González, V. Palomares, P. Serras and T. Rojo, J. Mater. Chem., 2012, 22, 17421
    DOI: 10.1039/C2JM33639A

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