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Issue 20, 2012
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A robust microporous metal–organic framework constructed from a flexible organic linker for highly selective sorption of methanol over ethanol and water

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Abstract

A microporous metal–organic framework MOF 1 [Zn(L)2(methanol)2] (H2L = (1R,3S)-1,2,2-trimethyl-3-(pyridin-4-ylcarbamoyl)cyclopentanecarboxylic acid) constructed from a flexible Zn2+ node and a flexible organic linker L was obtained by solvothermal reaction of diamond topology, and exhibits highly selective sorption of methanol over ethanol and water.

Graphical abstract: A robust microporous metal–organic framework constructed from a flexible organic linker for highly selective sorption of methanol over ethanol and water

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Publication details

The article was received on 02 Nov 2011, accepted on 30 Mar 2012 and first published on 17 Apr 2012


Article type: Paper
DOI: 10.1039/C2JM15604K
Citation: J. Mater. Chem., 2012,22, 10352-10355
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    A robust microporous metal–organic framework constructed from a flexible organic linker for highly selective sorption of methanol over ethanol and water

    Q. Huang, J. Cai, H. Wu, Y. He, B. Chen and G. Qian, J. Mater. Chem., 2012, 22, 10352
    DOI: 10.1039/C2JM15604K

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