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Issue 11, 2012
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A simple and efficient approach for the palladium-catalyzed ligand-free Suzuki reaction in water

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Abstract

A general and efficient protocol is described for the palladium-catalyzed ligand-free and aerobic Suzuki reaction in water in the absence of any additive. The results demonstrate that the base played a crucial role in the high efficiency. The Pd(OAc)2/(i-Pr)2NH/H2O system showed the highest catalytic activity towards the Suzuki reaction of a wide range of aryl halides bearing hydrophilic or hydrophobic groups.

Graphical abstract: A simple and efficient approach for the palladium-catalyzed ligand-free Suzuki reaction in water

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Publication details

The article was received on 16 Jul 2012, accepted on 31 Aug 2012 and first published on 04 Sep 2012


Article type: Communication
DOI: 10.1039/C2GC36098E
Citation: Green Chem., 2012,14, 2999-3003
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    A simple and efficient approach for the palladium-catalyzed ligand-free Suzuki reaction in water

    C. Liu, Y. Zhang, N. Liu and J. Qiu, Green Chem., 2012, 14, 2999
    DOI: 10.1039/C2GC36098E

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