Issue 6, 2012
From the journal:

Green Chemistry

Mechanosynthesis of nitrosobenzenes: a proof-of-principle study in combining solvent-free synthesis with solvent-free separations†

Igor Huskić,a   Ivan Halasz,*a   Tomislav Friščićb  and  Hrvoj Vančika  

* Corresponding authors

a Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, HR-10002 Zagreb, Croatia
E-mail: ihalasz@chem.pmf.hr
Fax: +385 1 460 6401
Tel: +385 1 460 6416

b Department of Chemistry, McGill University, 801 Sherbrooke St. W., H3A 0B8 Montreal, Canada

Abstract

Mechanochemical Oxone oxidation of selected para-substituted anilines was used as a rapid and solvent-free route to nitrosobenzenes; besides avoiding bulk solvents and short reaction times, this method exploits high vapour pressures of nitrosobenzenes for the solvent-free separation of the product by sublimation, demonstrating an entirely solvent-free route to chemical synthesis and product isolation.

Graphical abstract: Mechanosynthesis of nitrosobenzenes: a proof-of-principle study in combining solvent-free synthesis with solvent-free separations

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Article information

DOI
https://doi.org/10.1039/C2GC35410A
Article type
Communication
Submitted
20 Mar 2012
Accepted
17 Apr 2012
First published
18 Apr 2012

Green Chem., 2012,14, 1597-1600

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Mechanosynthesis of nitrosobenzenes: a proof-of-principle study in combining solvent-free synthesis with solvent-free separations

I. Huskić, I. Halasz, T. Friščić and H. Vančik, Green Chem., 2012, 14, 1597 DOI: 10.1039/C2GC35410A

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