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Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Fudan University, Shanghai 200433, China
; Fax: (+86)-21-51630318
; Tel: (+86)-21-51630318
Energy Environ. Sci., 2012,5, 6652-6667
08 Dec 2011,
22 Feb 2012
First published online
23 Feb 2012
Li-ion batteries are one of the most promising electrochemical power sources to be widely used in portable electronics, electric vehicles, and stationary energy storage systems. Ti-based materials have been intensively investigated as important anodes for Li-ion batteries due to their high safety and excellent cycling stability. The present work reviews the latest advances in the exploration and development of Ti-based compounds, such as Li4Ti5O12, Li2Ti3O7, TiO2-B and H2Ti3O7, as high performance anode materials for Li-ion batteries. The relationship between the preparation, composition, structure, morphology and electrochemical performance are summarized and analyzed. Further, the related advancements and challenges in practical energy applications are discussed.
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Energy & Environmental Science
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