Issue 48, 2012
From the journal:

Dalton Transactions

A Ru-isocyanate initiator for fast, living, precisely controlled ring-opening metathesis polymerization at ambient temperatures†

Sebastien Monfette,a   Joshua Marleau-Gillette,a   Jay C. Conrad,a   Robert McDonaldb  and  Deryn E. Fogg*a  

* Corresponding authors

a Department of Chemistry, Centre for Catalysis Research and Innovation, University of Ottawa, Ottawa, Canada
E-mail: dfogg@uottawa.ca
Tel: +1 613-562-5800 ext. 6057

b Department of Chemistry, University of Alberta, Edmonton, Alberta, Canada

Abstract

The new complex Ru(NCO)2(IMes)(py)2([double bond, length as m-dash]CHPh) is the first ruthenium metathesis initiator capable of fast, controlled living polymerization of functionalized norbornenes at room temperature, irrespective of monomer bulk.

Graphical abstract: A Ru-isocyanate initiator for fast, living, precisely controlled ring-opening metathesis polymerization at ambient temperatures

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Article information

DOI
https://doi.org/10.1039/C2DT32568C
Article type
Communication
Submitted
13 Sep 2012
Accepted
26 Oct 2012
First published
29 Oct 2012

Dalton Trans., 2012,41, 14476-14479

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A Ru-isocyanate initiator for fast, living, precisely controlled ring-opening metathesis polymerization at ambient temperatures

S. Monfette, J. Marleau-Gillette, J. C. Conrad, R. McDonald and D. E. Fogg, Dalton Trans., 2012, 41, 14476 DOI: 10.1039/C2DT32568C

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