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Issue 39, 2012
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The group 7 metal carbonyl complexes from a stable heteroleptic silylene PhC(NtBu)2SiNPh2

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Abstract

Two silylene transition metal complexes were prepared by reacting stable N-heterocyclic silylene L {L = PhC(NtBu)2SiNPh2}with Mn2(CO)10 and Re2(CO)10 respectively in a 2 : 1 ratio to yield [L2Mn(CO)4]+[Mn(CO)5] (1) and [L2Re(CO)4]+[Re(CO)5] (2). Both complexes 1 and 2 were characterized by NMR spectroscopy, EI-MS spectrometry and elemental analysis. The molecular structures of complexes 1 and 2 were established by single crystal X-ray analysis.

Graphical abstract: The group 7 metal carbonyl complexes from a stable heteroleptic silylene PhC(NtBu)2SiNPh2

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Publication details

The article was received on 16 Jul 2012, accepted on 10 Aug 2012 and first published on 13 Aug 2012


Article type: Paper
DOI: 10.1039/C2DT31578E
Citation: Dalton Trans., 2012,41, 12096-12100
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    The group 7 metal carbonyl complexes from a stable heteroleptic silylene PhC(NtBu)2SiNPh2

    R. Azhakar, H. W. Roesky, J. J. Holstein and B. Dittrich, Dalton Trans., 2012, 41, 12096
    DOI: 10.1039/C2DT31578E

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