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Issue 47, 2012
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Low melting Li/K/Cs acetate salt mixtures as new ionic media for catalytic applications – first physico-chemical characterization

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Abstract

In order to expand the temperature limits of Supported Ionic Liquid Phase (SILP) or Solid Catalyst with Ionic Liquid Layer (SCILL) systems to higher operation temperatures, the mixture of lithium acetate, potassium acetate, and caesium acetate (molar ratio of 0.2/0.275/0.525) has been studied in detail. Physico-chemical properties of the bulk melt are reported together with stability data of the modern salt on various solid support materials showing attractive properties for many potential high temperature applications.

Graphical abstract: Low melting Li/K/Cs acetate salt mixtures as new ionic media for catalytic applications – first physico-chemical characterization

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Publication details

The article was received on 15 Jul 2012, accepted on 14 Sep 2012 and first published on 14 Sep 2012


Article type: Paper
DOI: 10.1039/C2DT31568H
Citation: Dalton Trans., 2012,41, 14433-14438
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    Low melting Li/K/Cs acetate salt mixtures as new ionic media for catalytic applications – first physico-chemical characterization

    S. Bajus, A. Deyko, A. Bösmann, F. Maier, H. Steinrück and P. Wasserscheid, Dalton Trans., 2012, 41, 14433
    DOI: 10.1039/C2DT31568H

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