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Issue 44, 2012
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Slow magnetic relaxation in homoleptic trispyrazolylborate complexes of neodymium(III) and uranium(III)

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Abstract

Lanthanide- and actinide-based single-molecule magnets are rapidly gaining prominence due to the unique properties of f-orbitals, yet no direct comparison of slow magnetic relaxation of an isostructural and valence isoelectronic lanthanide and actinide complex exists. We present the dynamic magnetic properties of two f-element single-molecule magnets, NdTp3 and UTp3 (Tp = trispyrazolylborate), demonstrating that, although neither complex displays the full anisotropy barrier predicted from its electronic structure, relaxation is slower in the uranium congener. Magnetic dilution studies performed with NdTp3 reveal that, while intermolecular interactions partially account for the faster relaxation dynamics, they are not uniquely responsible.

Graphical abstract: Slow magnetic relaxation in homoleptic trispyrazolylborate complexes of neodymium(iii) and uranium(iii)

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Publication details

The article was received on 25 Jun 2012, accepted on 26 Jul 2012 and first published on 30 Jul 2012


Article type: Communication
DOI: 10.1039/C2DT31352A
Citation: Dalton Trans., 2012,41, 13572-13574
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    Slow magnetic relaxation in homoleptic trispyrazolylborate complexes of neodymium(III) and uranium(III)

    J. D. Rinehart and J. R. Long, Dalton Trans., 2012, 41, 13572
    DOI: 10.1039/C2DT31352A

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