Issue 31, 2012
From the journal:

Dalton Transactions

Encapsulation of a guest sodium cation by iron(iii) tris-(hydroxamate)s†

Irina A. Golenya,a   Elzbieta Gumienna-Kontecka,*b   Aleksander N. Boyko,a   Matti Haukkac  and  Igor O. Fritsky*a  

* Corresponding authors

a Department of Chemistry, National Taras Shevchenko University, 01601 Kiev, Ukraine
E-mail: ifritsky@univ.kiev.ua
Fax: +38 044 239 33 93
Tel: +38 044 239 33 93

b Faculty of Chemistry, University of Wroclaw, F. Joliot-Curie 14, 50-383 Wroclaw, Poland
E-mail: elzbieta.gumienna-kontecka@chem.uni.wroc.pl
Tel: +48713757342

c Department of Chemistry, University of Joensuu, P.O. Box 111, Joensuu, Finland
E-mail: matti.haukka@uef.fi

Abstract

An unprecedented encapsulation of an exogenous sodium ion by iron(III) tris(hydroxamate)s was observed upon crystallization of an iron(III) complex with isonicotinylhydroxamic acid. The sodium cation is bound by bridging coordination of the amide oxygen atoms from two mononuclear iron(III) fac-tris(hydroxamate)s.

Graphical abstract: Encapsulation of a guest sodium cation by iron(iii) tris-(hydroxamate)s

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Article information

DOI
https://doi.org/10.1039/C2DT30669G
Article type
Paper
Submitted
23 Mar 2012
Accepted
15 Jun 2012
First published
18 Jun 2012

Dalton Trans., 2012,41, 9427-9430

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Encapsulation of a guest sodium cation by iron(III) tris-(hydroxamate)s

I. A. Golenya, E. Gumienna-Kontecka, A. N. Boyko, M. Haukka and I. O. Fritsky, Dalton Trans., 2012, 41, 9427 DOI: 10.1039/C2DT30669G

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