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Issue 33, 2012
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Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(IV)

Fengyan Li,ab  De-Liang Long,*a  Jamie M. Cameron,a  Haralampos N. Miras,a  Chullikkattil P. Pradeep,a  Lin Xub  and  Leroy Cronin*a 
Author affiliations

* Corresponding authors

a WestCHEM, School of Chemistry, University of Glasgow, Joseph Black Building, University Avenue, Glasgow, UK G12 8QQ
E-mail: Deliang.Long@glasgow.ac.uk, Lee.Cronin@glasgow.ac.uk
Fax: +44 (0)141 330 4888
Tel: +44 (0)141 330 6650

b Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, People's Republic of China
Fax: +86 431 85099668
Tel: +86 431 85099668

Abstract

The heteropolyvanadate cluster [(n-C4H9)4N]4[MnIVV12O34]·2CH3CN has been isolated by cation exchange from K10[(MnIVV11O32)2]·20H2O. The structural transformation has been confirmed by X-ray single crystal structure determination and cryospray ionization mass spectrometry measurements.

Graphical abstract: Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(iv)

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Publication details

The article was received on 03 Apr 2012, accepted on 03 May 2012 and first published on 04 May 2012


Article type: Communication
DOI: 10.1039/C2DT30627A
Citation: Dalton Trans., 2012,41, 9859-9862
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    Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(IV)

    F. Li, D. Long, J. M. Cameron, H. N. Miras, C. P. Pradeep, L. Xu and L. Cronin, Dalton Trans., 2012, 41, 9859
    DOI: 10.1039/C2DT30627A

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