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Issue 33, 2012
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Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(IV)

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Abstract

The heteropolyvanadate cluster [(n-C4H9)4N]4[MnIVV12O34]·2CH3CN has been isolated by cation exchange from K10[(MnIVV11O32)2]·20H2O. The structural transformation has been confirmed by X-ray single crystal structure determination and cryospray ionization mass spectrometry measurements.

Graphical abstract: Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(iv)

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Publication details

The article was received on 03 Apr 2012, accepted on 03 May 2012 and first published on 04 May 2012


Article type: Communication
DOI: 10.1039/C2DT30627A
Citation: Dalton Trans., 2012,41, 9859-9862
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    Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(IV)

    F. Li, D. Long, J. M. Cameron, H. N. Miras, C. P. Pradeep, L. Xu and L. Cronin, Dalton Trans., 2012, 41, 9859
    DOI: 10.1039/C2DT30627A

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