Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(IV)

Fengyan Li; De-Liang Long; Jamie M. Cameron; Haralampos N. Miras; Chullikkattil P. Pradeep; Lin Xu; Leroy Cronin

doi:10.1039/C2DT30627A

Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(IV)

Fengyan Li,^a^b De-Liang Long,*^a Jamie M. Cameron,^a Haralampos N. Miras,^a Chullikkattil P. Pradeep,^a Lin Xu^b and Leroy Cronin*^a

Author affiliations

* Corresponding authors

^a WestCHEM, School of Chemistry, University of Glasgow, Joseph Black Building, University Avenue, Glasgow, UK G12 8QQ
E-mail: Deliang.Long@glasgow.ac.uk, Lee.Cronin@glasgow.ac.uk
Fax: +44 (0)141 330 4888
Tel: +44 (0)141 330 6650

^b Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, People's Republic of China
Fax: +86 431 85099668
Tel: +86 431 85099668

Abstract

The heteropolyvanadate cluster [(n-C₄H₉)₄N]₄[Mn^IVV₁₂O₃₄]·2CH₃CN has been isolated by cation exchange from K₁₀[(Mn^IVV₁₁O₃₂)₂]·20H₂O. The structural transformation has been confirmed by X-ray single crystal structure determination and cryospray ionization mass spectrometry measurements.

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Publication details

The article was received on 03 Apr 2012, accepted on 03 May 2012 and first published on 04 May 2012

Article type: Communication

DOI: 10.1039/C2DT30627A

Citation: Dalton Trans., 2012,41, 9859-9862

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Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(IV)

F. Li, D. Long, J. M. Cameron, H. N. Miras, C. P. Pradeep, L. Xu and L. Cronin, Dalton Trans., 2012, 41, 9859
DOI: 10.1039/C2DT30627A
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Dalton Transactions

Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(IV)

Abstract

Supplementary files

Publication details

Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(IV)

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