Issue 25, 2012
From the journal:

Dalton Transactions

Triaryl-1,3,5-triazinane-2,4,6-triones functionalized with electron-rich Fe(ii) and Ru(ii) acetylide complexes: new organometallic octupoles with large hyperpolarizabilities†

Alexander Trujillo,a   Romain Veillard,a   Gilles Argouarch,a   Thierry Roisnel,a   Anu Singh,b   Isabelle Ledoux*b  and  Frédéric Paul*a  

* Corresponding authors

a Sciences Chimiques de Rennes, UMR CNRS 6226, Université de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex, France
E-mail: frederic.paul@univ-rennes1.fr

b Laboratoire de Photonique Quantique et Moléculaire (CNRS UMR 8537), ENS Cachan, 61 Avenue du Président Wilson, F-94235 Cachan Cedex, France
E-mail: ledoux@lpqm.ens-cachan.fr

Abstract

The synthesis and study of a series of trinuclear organometallic triaryl-1,3,5-triazinane-2,4,6-triones functionalized by d6-transition metal acetylides complexes at their periphery are reported. Remarkably large hyperpolarizabilities, far superior to those of related purely organic derivatives, are measured by hyper-Rayleigh scattering (HRS) for these new octupolar chromophores.

Graphical abstract: Triaryl-1,3,5-triazinane-2,4,6-triones functionalized with electron-rich Fe(ii) and Ru(ii) acetylide complexes: new organometallic octupoles with large hyperpolarizabilities

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Article information

DOI
https://doi.org/10.1039/C2DT30555K
Article type
Communication
Submitted
08 Mar 2012
Accepted
02 Apr 2012
First published
02 Apr 2012

Dalton Trans., 2012,41, 7454-7456

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Triaryl-1,3,5-triazinane-2,4,6-triones functionalized with electron-rich Fe(II) and Ru(II) acetylide complexes: new organometallic octupoles with large hyperpolarizabilities

A. Trujillo, R. Veillard, G. Argouarch, T. Roisnel, A. Singh, I. Ledoux and F. Paul, Dalton Trans., 2012, 41, 7454 DOI: 10.1039/C2DT30555K

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