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Issue 33, 2012
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A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor

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Abstract

A 1,3-dipolar cycloaddition reaction taking place quantitatively between propiolic acid “guests” and azide functions previously attached to binding sites within the cavity of a {Mo132}-type Keplerate reproducibly gives a 2 : 1 ratio of 1,4- and 1,5-triazoles.

Graphical abstract: A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor

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Publication details

The article was received on 01 Mar 2012, accepted on 20 Jun 2012 and first published on 10 Jul 2012


Article type: Communication
DOI: 10.1039/C2DT30502J
Citation: Dalton Trans., 2012,41, 9852-9854
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    A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor

    C. Besson, S. Schmitz, K. M. Capella, S. Kopilevich, I. A. Weinstock and P. Kögerler, Dalton Trans., 2012, 41, 9852
    DOI: 10.1039/C2DT30502J

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