Issue 33, 2012
From the journal:

Dalton Transactions

A fluorophosphate-based inverse Keggin structure†

John Fielden,ab   Kyle Quasdorf,a   Leroy Croninc  and  Paul Kögerler*ab  

* Corresponding authors

a Ames Laboratory, Iowa State University, Ames, IA 50011, USA

b Institute of Inorganic Chemistry, RWTH Aachen University, 52074 Aachen, Germany
E-mail: paul.koegerler@ac.rwth-aachen.de

c WestCHEM, University of Glasgow, Glasgow, UK

Abstract

An unusual PFO32−-templated “inverse Keggin” polyanion, [Mo12O46(PF)4]4−, has been isolated from the degradation reaction of an {Mo132}-type Keplerate to [PMo12O40]3− by [Cu(MeCN)4](PF6) in acetonitrile. 31P-NMR studies suggest a structure-directing role for [Cu(MeCN)4]+ in the formation of the highly unusual all-inorganic inverse Keggin structure.

Graphical abstract: A fluorophosphate-based inverse Keggin structure

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Article information

DOI
https://doi.org/10.1039/C2DT30501A
Article type
Communication
Submitted
01 Mar 2012
Accepted
17 Jul 2012
First published
17 Jul 2012

Dalton Trans., 2012,41, 9876-9878

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A fluorophosphate-based inverse Keggin structure

J. Fielden, K. Quasdorf, L. Cronin and P. Kögerler, Dalton Trans., 2012, 41, 9876 DOI: 10.1039/C2DT30501A

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