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Issue 33, 2012
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A fluorophosphate-based inverse Keggin structure

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Abstract

An unusual PFO32−-templated “inverse Keggin” polyanion, [Mo12O46(PF)4]4−, has been isolated from the degradation reaction of an {Mo132}-type Keplerate to [PMo12O40]3− by [Cu(MeCN)4](PF6) in acetonitrile. 31P-NMR studies suggest a structure-directing role for [Cu(MeCN)4]+ in the formation of the highly unusual all-inorganic inverse Keggin structure.

Graphical abstract: A fluorophosphate-based inverse Keggin structure

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Publication details

The article was received on 01 Mar 2012, accepted on 17 Jul 2012 and first published on 17 Jul 2012


Article type: Communication
DOI: 10.1039/C2DT30501A
Citation: Dalton Trans., 2012,41, 9876-9878
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    A fluorophosphate-based inverse Keggin structure

    J. Fielden, K. Quasdorf, L. Cronin and P. Kögerler, Dalton Trans., 2012, 41, 9876
    DOI: 10.1039/C2DT30501A

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